The zwitterionic title compound, [Mn(C 10 H 8 O 5 )(C 12 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, has the Mn atom in an octahedral geometry that comprises the O atom of the 2-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive hydrogenbondin
Triaqua[3-(4-carboxylatophenoxy)propionato-κO](1,10-phenanthroline-κ2N,N′)zinc(II)
✍ Scribed by Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 381 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, [Zn(C~10~H~8~O~5~)(C~12~H~8~N~2~)(H~2~O)~3~], is a neutral mononuclear complex. The Zn atom has a distorted octahedral geometry involving one O atom of the 3-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive hydrogen-bonding and π–π stacking interactions [centroid–centroid distance = 3.656 (3) Å] construct a three-dimensional supramolecular network.
📜 SIMILAR VOLUMES
Triaqua(benzene-1,2-dicarboxylato-jO)-(1,10-phenanthroline-j 2 N,N 0 0 0 )zinc(II) monohydrate
The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa
In the crystal structure of the polymeric title compound, [Mn(C~10~H~8~N~2~)(C~10~H~8~O~5~)(H~2~O)]~__n__~, the Mn^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion and is covalently bonded (through one O atom) by the aliphatic carbox
In the crystal structure of the polymeric title compound, [Co(C~10~H~8~O~5~)(C~10~H~8~N~2~)(H~2~O)]~__n__~, the Co^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion, and is covalently bonded (through one O atom) by the aliphatic carbo