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Triaqua[2-(4-carboxylatophenoxy)propionato-κO](1,10-phenanthroline-κ2N,N′)manganese(II) monohydrate

✍ Scribed by Xiao, Ying-Hui ;Kong, Li-Li ;Gao, Shan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
447 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The zwitterionic title compound, [Mn(C 10 H 8 O 5 )(C 12 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O, has the Mn atom in an octahedral geometry that comprises the O atom of the 2-(4-carboxylatophenoxy)propionate group, two N atoms of the 1,10-phenanthroline ligand and three water molecules. Extensive hydrogenbonding andstacking interactions lead to a threedimensional supramolecular network. Related literature For the cobalt(II) and nickel(II) complexes of the same carboxylic acid, see: Deng et al. (2007a,b). Experimental Crystal data [Mn(C 10 H 8 O 5 )(C 12 H 8 N 2 )-(H 2 O) 3 ]ÁH 2 O M r = 515.37 Triclinic, P1 a = 7.5457 (15) A b = 11.073 (2) A ˚c = 15.372 (3) A = 106.16 (3) = 99.53 (3) = 103.14 (3) V = 1164.8 (5) A ˚3 Z = 2 Mo K radiation = 0.62 mm À1 T = 295 (2) K 0.38 Â 0.25 Â 0.17 mm Data collection Rigaku R-AXIS RAPID diffractometer Absorption correction: multi-scan (ABSCOR; Higashi, 1995) T min = 0.826, T max = 0.893 11565 measured reflections 5280 independent reflections 3105 reflections with I > 2(I) R int = 0.036 Refinement R[F 2 > 2(F 2 )] = 0.038 wR(F 2 ) = 0.100 S = 1.12 5280 reflections 332 parameters H atoms treated by a mixture of independent and constrained refinement Á max = 0.56 e A ˚À3

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