trans,trans,trans-Diacetonitriledibromobis(4-fluoroaniline)nickel(II)
✍ Scribed by Fawcett, John ;Sicilia, Fabrizio ;Solan, Gregory A
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 146 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [CoCl~2~(C~6~H~7~N)~2~(C~2~H~6~O)~2~], was obtained unintentionally as the product of an attempted synthesis of a polycarboxylate-bridged network complex of cobalt(II) using aniline as a base to deprotonate the organic acid. The molecule is centrosymmetric, so pairs of equivalent
In the title crystal structure, [Ni 2 Cl 4 {CH 2 (CH 2 CH 2 PPr i 2 ) 2 } 2 ], there are two independent molecules, one of which lies on a crystallographic inversion center. The Ni II atoms in each dinuclear molecule are in slightly distorted square-planar geometries. The two independent molecules h
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.027 wR factor = 0.063 Data-to-parameter ratio = 19.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The diazide platinum(II) complex, [Pt(N~3~)~2~(PPh~3~)~2~], reacts with 4-FC~6~H~4~CN under microwave irradiation to give the corresponding neutral title bis(tetrazolate) complex __trans__-[Pt(N~4~CR)~2~(PPh~3~)~2~] or [Pt(C~7~H~4~FN~4~)~2~(C~18~H~15~P)~2~]. The Pt^II^ atom lies on a crystallographi