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trans-Bis[5-(4-fluorophenyl)tetrazolato]bis(triphenylphosphine)platinum(II)

✍ Scribed by Mukhopadhyay, Suman ;Lasri, Jamal ;Guedes da Silva, M. Fátima C. ;Charmier, M. Adília J. ;Pombeiro, Armando J. L.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
517 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The diazide platinum(II) complex, [Pt(N~3~)~2~(PPh~3~)~2~], reacts with 4-FC~6~H~4~CN under microwave irradiation to give the corresponding neutral title bis(tetrazolate) complex trans-[Pt(N~4~CR)~2~(PPh~3~)~2~] or [Pt(C~7~H~4~FN~4~)~2~(C~18~H~15~P)~2~]. The Pt^II^ atom lies on a crystallographic inversion centre and is coordinated by two N atoms and two P atoms in a slightly distorted square-planar environment. The unique tetrazolate ring is essentially planar and the corresponding C...;N and N...;N bond distances lie in the range 1.317 (3)–1.349 (3) Å.

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