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trans-Dichloro­bis(tris­{4-[(dimethyl­amino)meth­yl]phen­yl}phosphine)platinum(II)

✍ Scribed by Lutz, Martin ;Spek, Anthony L. ;Kreiter, Robert ;Klein Gebbink, Robertus J. M. ;Koten, Gerard van

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
228 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Crystals of the title compound, [PtCl 2 (C 27 H 36 N 3 P) 2 ], as the trans-isomer were obtained from the originally formed cisisomer after standing for more than four months in solution.

In the crystal structure, the Pt atom is located on an inversion centre, which makes the molecular structure similar to the triphenylphosphine analogue. The amino groups are pyramidal and do not interact with Pt atoms or hydrogen-bond donors.

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