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trans-Bis­(carbazol-3-yl­ethynyl)­bis­(tri-n-butyl­phosphine)­platinum(II)

✍ Scribed by Khan, Muhammad S. ;Al-Saadi, Rahma K. M. ;Male, Louise ;Raithby, Paul R. ;Bjernemose, Jens K.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
307 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Pt(C 12 H 27 P) 2 (C 14 H 8 N) 2 ], is a mononuclear Pt II di-yne exhibiting %-conjugation along the molecular backbone. It is used as a model species for rigidrod platinum poly yne compounds of which it is a precursor. Such compounds are of interest due to the extended %conjugation through the hetero-aromatic linker unit in the backbone.

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