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trans,trans-Bis[μ-1,5-bis­(diisopropyl­phos­phino)­pentane-κ2P:P′]bis­[dichloro­nickel(II)]

✍ Scribed by Castonguay, Annie ;Beauchamp, André L. ;Zargarian, Davit

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
219 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title crystal structure, [Ni 2 Cl 4 {CH 2 (CH 2 CH 2 PPr i 2 ) 2 } 2 ], there are two independent molecules, one of which lies on a crystallographic inversion center. The Ni II atoms in each dinuclear molecule are in slightly distorted square-planar geometries. The two independent molecules have markedly different conformations due to the relative orientations of the Cl/Ni/Cl groups with respect to the plane defined by the four P and the two Ni II atoms.

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