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Transition Probabilities in the B1Σ+–X1Σ+ and the B1Σ+–A1Π Electronic Systems of MgO

✍ Scribed by John W. Daily; Christopher Dreyer; Angel Abbud-Madrid; Melvyn C. Branch

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
264 KB
Volume
214
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

Transition probabilities for the B 1 + -X 1 + and the B 1 + -A 1 electronic systems are presented for v = 0-4 and J = 0-150 in each electronic state. The functional form of the electronic transition moment for the B-X transition is taken from published ab initio results. The B-A moment is assumed to have the same form and is scaled using empirical branching ratio data. The R e (r ) are used with Rydberg-Klein-Rees (RKR) wavefunctions to calculate transition probabilities for v = 0-4 and J = 0-150. The RKR potentials were calculated based on empirical spectroscopic constants.

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