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The Radial Hamiltonians for the X1Σ+ and B1Σ+ States of HCl

✍ Scribed by John A. Coxon; Photos G. Hajigeorgiou

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
231 KB
Volume
203
Category
Article
ISSN
0022-2852

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✦ Synopsis

The results from the separate analyses demonstrate clearly that the two hamiltonian operators are essentially equivalent, both achieving equally satisfactory representations of the spectral data, and furnishing virtually identical Born-Oppenheimer potential functions. Fully quantum-mechanical vibrational eigenvalues and rotational perturbation series parameters B v -O v are presented for the lower levels of the X 1 ⌺ ϩ ground state for which infrared and/or microwave data are available (v Љ Յ 7 for H 35 Cl and H 37 Cl, v Љ Յ 10 for D 35 Cl and D 37 Cl). These parameters collectively reproduce the corresponding spectroscopic line positions included in our fit to within the uncertainties of the measurements.

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