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Transition Probabilities in theA1Π–X1Σ+System of CS

✍ Scribed by Christopher A. Mahon; Anna Stampanoni; Jorge Luque; David R. Crosley

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
210 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

Fluorescence intensity ratios in the A 1 P-X 1 S / band system of the CS radical, with £ Å 0-4, have been measured and analyzed using the r-centroid approximation. The radicals were generated in a microwave discharge and excited with laser radiation. Experimental branching ratios, together with Franck-Condon factors and r-centroids derived from RKR wavefunctions, have been used to evaluate the electronic transition moment, which is found to be linear with a slope of 00.46 A ˚01 .

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