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Transformation of an isocyanide ligand in the coordination sphere of an osmium cluster. Reactions of osmium isocyanide complexes with amines

✍ Scribed by Lin, Yen Wen; Gau, Han Mou; Wen, Yuh Sheng; Lu, Kuang Lieh


Book ID
127167689
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
396 KB
Volume
11
Category
Article
ISSN
0276-7333

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Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between an electronpoor 2-hydroxybenzaldehyde derivative and a secondary amine in the presence of silica gel proceeds smoothly at room temperature to afford benzo[b]furan derivatives in high yields.