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C–H Bond Activation of the Methyl Group of the Supporting Ligand in an Osmium(III) Complex upon Reaction with H 2 O 2 : Formation of an Organometallic Osmium(IV) Complex

✍ Scribed by Sugimoto, Hideki; Ashikari, Kenji; Itoh, Shinobu


Book ID
118201836
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
494 KB
Volume
52
Category
Article
ISSN
0020-1669

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✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th