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Extended normal coordinate analysis of an (arene)osmium(II) complex with the inclusion of the ring ligand

✍ Scribed by T. Polzer; W. Kiefer

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 682 KB
Volume: 472
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(94)80216-5

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## Abstract The five‐coordinate compounds [MHCl(CO)(P__i__Pr~3~)~2~] (where 1a: M = Ru; 1b: M = Os) react with P__i__Pr~2~R\* [where R\* = CH(Me)Ph] to give the octahedral complexes __mer__‐[MHCl(CO)(P__i__Pr~2~R\*)~3~] (6 and 7). The lability of the phosphane __trans__ to the hydride is illustrate