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Transfer hydrogenation of diarylacetylenes by polymethylhydrosiloxane in the presence of the RhCl3-Aliquat 336 catalyst

โœ Scribed by Jochanan Blum; Gal Bitan; Sharon Marx; K.Peter C. Vollhardt


Publisher
Elsevier Science
Year
1991
Weight
496 KB
Volume
66
Category
Article
ISSN
0304-5102

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Selective C๎—ธC bond hydrogenation in unsa
โœ Ibrahim Amer; Tamar Bravdo; Jochanan Blum; K. Peter; C. Vollhardt ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 124 KB

The ion pair formed from aqueous rhodium trichloride and Aliquat 336 catalyzes the selective hydrogenation of olefinic C-C bonds of a variety of unsaturated nitro compounds in a two liquid phase system at 30ยฐC. Nitrobenzene gives, under these conditions, a mixture of aniline and nitrocyclohexane.