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Selective transfer hydrogenation of various unsaturated functions by polymethylhydrosiloxane in the presence of a recyclable rhodium catalyst

✍ Scribed by Jochanan Blum; Ilan Pri-Bar; Howard Alper


Publisher
Elsevier Science
Year
1986
Weight
478 KB
Volume
37
Category
Article
ISSN
0304-5102

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## Abstract A range of __α,β__‐unsaturated acids and esters have been selectively reduced to the corresponding saturated acid derivatives by hydrogen transfer. As the reducing agent, formic acid was used in the presence of Rh^I^ complexes formed with the powerful chiral ligand Ph‐binepine (**1**),