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Hydrogenation of arenes by the RhCl3-aliquat® 336 catalyst: Part 3. Selective reduction of polycyclic compounds

✍ Scribed by Ibrahim Amer; Hamdullah Amer; Rachel Ascher; Jochanan Blum; Yoel Sasson; K.Peter C. Vollhardt

Publisher
Elsevier Science
Year
1987
Weight
576 KB
Volume
39
Category
Article
ISSN
0304-5102

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📜 SIMILAR VOLUMES

Selective CC bond hydrogenation in unsa
Selective CC bond hydrogenation in unsaturated nitro compounds in the presence of the RhCl3-aliquat 336 catalyst system
✍ Ibrahim Amer; Tamar Bravdo; Jochanan Blum; K. Peter; C. Vollhardt 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 124 KB

The ion pair formed from aqueous rhodium trichloride and Aliquat 336 catalyzes the selective hydrogenation of olefinic C-C bonds of a variety of unsaturated nitro compounds in a two liquid phase system at 30°C. Nitrobenzene gives, under these conditions, a mixture of aniline and nitrocyclohexane.