In the title compound, [NiCl 2 (C 7 H 9 N) 4 ], where C 7 H 9 N is 3,5lutidine, the Ni II atom is coordinated by two Cl atoms and four N atoms from 3,5-lutidine groups. The geometry around the Ni II atom, which is located at a special position of symmetry 422, is octahedral. Molecules of the title c
trans-Dichlorotetrakis(dimethyl sulfide)ruthenium(II)
✍ Scribed by Abbasi, Alireza ;Azizi, Fereshteh ;Eriksson, Lars ;Sandström, Magnus
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 110 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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Alessio et al. (1991) have reported the structures of trans-RuCl 4 (DMSO) 2 , which has S-bonded DMSO ligands, and also mer-RuCl 3 (DMSO) 3 , which has one O-bonded DMSO. However, in that case, the O-bonded DMSO is trans to Cl rather than to S-bonded DMSO. That paper also reports a scheme for the
The title mononuclear ruthenium (IV) complex, (C 8 H 20 N)[Ru-(C 8 H 9 S) 3 Cl 2 ]ÁCH 2 Cl 2 , contains the trigonal {Ru(Sxylyl) 3 } core (xylyl is 2,6-dimethylphenyl), with S-Ru-S angles in the range 118.07 (6)-123.45 (6) . The coordination geometry of the central Ru atom is trigonal-bipyramidal, w