Tetrakis(3,5-lutidine)dichloronickel(II)
✍ Scribed by Xu, Xiang-Sheng ;Lü, Ya-Ping ;Deng, Dong-Shun ;Hu, Mao-Lin ;Jin, Zhi-Min
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 342 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [NiCl 2 (C 7 H 9 N) 4 ], where C 7 H 9 N is 3,5lutidine, the Ni II atom is coordinated by two Cl atoms and four N atoms from 3,5-lutidine groups. The geometry around the Ni II atom, which is located at a special position of symmetry 422, is octahedral. Molecules of the title compound are connected by C-HÁ Á ÁCl intermolecular hydrogen bonds and C-HÁ Á Á interactions to form a three-dimensional structure.
📜 SIMILAR VOLUMES
In the title mononuclear nickel(II) complex, [Ni(C 3 H 4 N 2 ) 4 ]-(NO 3 ) 2 , the Ni II atom is four-coordinated in a square-planar geometry by four N atoms from four imidazole ligands. The nitrate anions are linked to the nickel(II) complex cations through intermolecular N-HÁ Á ÁO hydrogen bonds.