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cis-trans-Tetra­chloro­bis(dimethyl sulfide-κS)tin

✍ Scribed by Ruth, Kai ;Lerner, Hans-Wolfram ;Bolte, Michael

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
316 KB
Volume
61
Category
Article
ISSN
1600-5368

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The title compound, [RhCl 3 (C 2 H 6 S) 3 ], exists as discrete molecules in which the Rh III atom is coordinated by three S atoms from the dimethyl sulfide molecules and three Cl atoms in a mer-octahedral configuration. ## Related literature For the related dimethyl sulfoxide compound, see Abbas

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The title compound, [Pt 2 Cl 2 (C 6 H 5 ) 2 (C 2 H 6 OS) 2 ] or [Pt("-Cl)Ph(dmso)] 2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is c