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Tetra­ethyl­ammonium dichloro­tris(2,6-dimethyl­phenyl­sulfanyl-κS)ruthenium dichloro­methane solvate

✍ Scribed by Song, Yan-Wei ;Yu, Zhan ;Zhang, Qian-Feng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
135 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title mononuclear ruthenium (IV) complex, (C 8 H 20 N)[Ru-(C 8 H 9 S) 3 Cl 2 ]ÁCH 2 Cl 2 , contains the trigonal {Ru(Sxylyl) 3 } core (xylyl is 2,6-dimethylphenyl), with S-Ru-S angles in the range 118.07 (6)-123.45 (6) . The coordination geometry of the central Ru atom is trigonal-bipyramidal, with two Cl atoms in the axial positions. The Ru-S and Ru-Cl bond lengths are 2.1918 (18)-2.2046 (19) and 2.378 (2)-2.385 (2) A ˚, respectively.

📜 SIMILAR VOLUMES

cis,cis-μ-2,3,5,6-Tetra-2-pyridylpyrazin
cis,cis-μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ3N1,N2,N6:κ3N3,N4,N5-bis­[dichloro­(dimethyl sulfoxide-κS)ruthenium(II)] dihydrate acetone disolvate
✍ Hadadzadeh, Hassan ;Yap, Glenn P. A. ;Crutchley, Robert J. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

Single-crystal X-ray study T = 120 K Mean (C-C) = 0.009 A Some non-H atoms missing R factor = 0.066 wR factor = 0.176 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.