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trans-Dichlorobis{2-[2-(4-methoxyphenyl)ethenyl]-5-methyl-1,3-benzoxazole-κN}cobalt(II)

✍ Scribed by Jia, Zhen-Shan ;Liu, Hui-Min ;Zheng, Yan ;Zhang, Wen-Qin


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
261 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.050 wR factor = 0.121 Data-to-parameter ratio = 16.9

For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Dichloro­[2,2′-(methyl­enedithio)bi-1,3-
✍ Zhao, Wen-Tao ;Liu, Hui-Min ;Zhang, Wen-Qin 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 248 KB

In the title complex, [CoCl~2~(C~7~H~6~N~2~S~4~)], 2,2′-(methylenedithio)bi-1,3-thiazole acts as a bidentate ligand and chelates one Co^II^ ion through the two N atoms to give an eight-membered symmetric unit. The Co^II^ ion is located on a twofold axis and displays a slightly distorted tetrahedral