In the title complex, [Cu(C 4 O 4 )(C 12 H 8 N 2 )(H 2 O) 2 ]Á2H 2 O, the Cu II centre exhibits a slightly distorted square-pyramidal coordination geometry, defined by two N atoms from a 1,10phenanthroline (phen) molecule, one O atom from an acetylenedicarboxylate dianion (ace 2À ), and two O atoms
trans-Diaqua(malonato)(1,10-phenanthroline)nickel(II) trihydrate
✍ Scribed by Zhao, Shu-Min ;Wu, Tian-Xing
- Book ID
- 104485720
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 184 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.026 wR factor = 0.071 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o