In the crystal structure of [PtBrH(C 18 H 15 P) 2 ]Á0.5C 7 H 8 , the Pt atom has a distorted square-planar environment, with the coordination sphere comprising hydride, bromide and mutually trans triphenylphosphine ligands.
trans-Bromohydridobis(triphenylphosphine)platinum(II)
✍ Scribed by Sivaramakrishna, Akella ;Su, Hong ;Moss, John R.
- Book ID
- 104489191
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 87 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Pt(CO 3 )(C 18 H 15 P) 2 ]ÁC 6 H 6 , has previously been reported by Cariati, Mason, Robertson & Ugo [Chem. Commun. (1967), p. 408]. However, no coordinates were published. We present here a redetermination of this structure using new intensity data. The Pt atom shows a distorte
In the structure of the title complex, [PtCl(C 18 H 15 P) 3 ]ClO 4 Á-2CH 2 Cl 2 , the coordination polyhedron with platinum as the central atom has a distorted square-planar geometry formed by three P atoms from three triphenylphosphine ligands and one Cl atom.