A third modification of [RuCl 2 (PPh 3 ) 3 ] has been characterized, this time as the title compound, [RuCl 2 (C 18 H 15 P) 3 ]Á-0.5CH 2 Cl 2 . As seen for the previous modifications, the complex has a distorted square-pyramidal geometry with an ortho-H atom 'blocking' the site trans to the apical P
Chlorotris(triphenylphosphine)platinum(II) perchlorate dichloromethane disolvate
✍ Scribed by Zhang, Ning ;Wu, Si-Lin ;Cao, Qian-Yong ;Liu, Jing-Hua
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 195 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the structure of the title complex, [PtCl(C 18 H 15 P) 3 ]ClO 4 Á-2CH 2 Cl 2 , the coordination polyhedron with platinum as the central atom has a distorted square-planar geometry formed by three P atoms from three triphenylphosphine ligands and one Cl atom.
📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize