𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dichloro­tris(triphenyl­phosphine)ruthenium(II) dichloro­methane hemisolvate

✍ Scribed by Cowley, Andrew R. ;Dilworth, Jonathan R. ;Maresca von Beckh W., Carlo A.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
180 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

A third modification of [RuCl 2 (PPh 3 ) 3 ] has been characterized, this time as the title compound, [RuCl 2 (C 18 H 15 P) 3 ]Á-0.5CH 2 Cl 2 . As seen for the previous modifications, the complex has a distorted square-pyramidal geometry with an ortho-H atom 'blocking' the site trans to the apical PPh 3 ligand. There is no evidence for a strong C-HÁ Á ÁRu interaction nor any specific directional force in the solid state.

📜 SIMILAR VOLUMES

Chloro­tris(triphenyl­phosphine)platinum
Chloro­tris(triphenyl­phosphine)platinum(II) perchlorate dichloro­methane disolvate
✍ Zhang, Ning ;Wu, Si-Lin ;Cao, Qian-Yong ;Liu, Jing-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 195 KB

In the structure of the title complex, [PtCl(C 18 H 15 P) 3 ]ClO 4 Á-2CH 2 Cl 2 , the coordination polyhedron with platinum as the central atom has a distorted square-planar geometry formed by three P atoms from three triphenylphosphine ligands and one Cl atom.

cis-Dichloro­bis(tri-2-furylphosphine)pa
cis-Dichloro­bis(tri-2-furylphosphine)palladium(II) dichloro­methane hemisolvate
✍ Meijboom, Reinout ;Muller, Alfred 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

In the title compound, cis-[PdCl 2 {P(C 4 H 3 O) 3 } 2 ]Á0.5CH 2 Cl 2 , where P(C 4 H 3 O) 3 is tri-2-furylphosphine, the Pd II centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) A ˚and Pd-Cl bond le

Dichloro­bis(triphenyl­phosphine)iron(II
Dichloro­bis(triphenyl­phosphine)iron(II)
✍ Seewald, Oliver ;Flörke, Ulrich ;Henkel, Gerald 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 260 KB