A third modification of [RuCl 2 (PPh 3 ) 3 ] has been characterized, this time as the title compound, [RuCl 2 (C 18 H 15 P) 3 ]Á-0.5CH 2 Cl 2 . As seen for the previous modifications, the complex has a distorted square-pyramidal geometry with an ortho-H atom 'blocking' the site trans to the apical P
Dichloro(η6-p-cymene)(triphenylphosphine)ruthenium(II)
✍ Scribed by Elsegood, Mark R.J. ;Smith, Martin B. ;Sanchez-Ballester, Noelia M.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 207 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.003 A Ê R factor = 0.024 wR factor = 0.061 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of the neutral Ru II complex [RuCl 2 ( 6 ± C 10 H 14 )(C 2 H 6 OS)] is reported. The overall coordination geometry about the ruthenium centre is best described as a typical `piano stool'. In the p-cymene ligand, the six C atoms of the arene ring are in a planar con®guration, as
The Pd atom in the title compound, __trans__-[PdCl~2~(C~6~H~15~N)(C~18~H~15~P)], is in an approximately square-planar environment, coordinated by one triethylamine, one triphenylphosphine and two __trans__ Cl ligands.