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A p-cymene-ruthenium(II)–DMSO complex, [(η6-C10H14)RuCl2(DMSO)]

✍ Scribed by Chandra, Manish ;Pandey, D. Shankar ;Puerta, M. Carmen ;Valerga, Pedro

Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
163 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of the neutral Ru II complex [RuCl 2 ( 6 ± C 10 H 14 )(C 2 H 6 OS)] is reported. The overall coordination geometry about the ruthenium centre is best described as a typical `piano stool'. In the p-cymene ligand, the six C atoms of the arene ring are in a planar con®guration, as expected.

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μ-Chloro-μ-hydrido-bis­[chloro(η6-p-cyme
μ-Chloro-μ-hydrido-bis­[chloro(η6-p-cymene)­ruthenium(II)](Ru—Ru): a second polymorph
✍ Therrien, Bruno ;Frein, Stéphane ;Süss-Fink, Georg 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 346 KB

The title dinuclear complex, [Ru 2 (C 10 H 14 )Cl 4 H], has twofold symmetry. The terminal Cl atom interacts with three CÐH H atoms of symmetry-related neighbouring molecules. These interactions play a key role in the packing arrangement.

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Bis(μ-η2-benzene-1,2-di­thiol­ato-κ3S,S′:S′)bis­[(η6-p-cymene)­ruthenium(II)]
✍ Cabeza, Javier A. ;García-Granda, Santiago ;Pérez-Priede, Monica ;Van der Maelen 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.010 A Ê R factor = 0.041 wR factor = 0.105 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.