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cis-Dichloro­bis(tri-2-furylphosphine)palladium(II) dichloro­methane hemisolvate

✍ Scribed by Meijboom, Reinout ;Muller, Alfred

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
158 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, cis-[PdCl 2 {P(C 4 H 3 O) 3 } 2 ]Á0.5CH 2 Cl 2 , where P(C 4 H 3 O) 3 is tri-2-furylphosphine, the Pd II centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd-P bond lengths are 2.2329 (10) and 2.2613 (9) A ˚and Pd-Cl bond lengths are 2.3393 (9) and 2.3501 (10) A ˚. The P-Pd-Cl angles are 89.07 (4) and 175.28 (4) . The average effective cone angle for the tri-2-furylphosphine was calculated to be 149 .

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