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trans-Dichloro­bis(tri-m-tolyl­phosphine)palladium(II)

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
154 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, trans-[PdCl~2~{P(C~7~H~7~)~3~}~2~], where P(C~7~H~7~)~3~ is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd—P and Pd—Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P—Pd—Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165°.

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