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trans-Bromo­hydridobis­(tri­phenyl­phosphine)­platinum toluene hemisolvate

✍ Scribed by Aldridge, Simon ;Coombs, Deborah ;Jones, Cameron

Book ID
104480655
Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
182 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of [PtBrH(C 18 H 15 P) 2 ]Á0.5C 7 H 8 , the Pt atom has a distorted square-planar environment, with the coordination sphere comprising hydride, bromide and mutually trans triphenylphosphine ligands.

📜 SIMILAR VOLUMES

cis-Dichloro­(di-tert-butyl­phosphine-κP
cis-Dichloro­(di-tert-butyl­phosphine-κP)(triphenyl­phosphine-κP)platinum(II) tetra­hydro­furan hemisolvate
✍ Chojnacki, Jaroslaw ;Robaszkiewicz, Andrzej ;Matern, Eberhard ;Baum, Elke ;Pikie 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 150 KB

The title compound, [PtCl~2~(C~8~H~19~P)(C~18~H~15~P)]·0.5C~4~H~8~O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-__tert__-butyl-2-trimethylsilyltriphosphine. The ^31^P{^1^H} NMR spectrum of the reaction mixture shows the formation of the title comp