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Total synthesis of (.+-.)-vernolepin and (.+-.)-vernomenin

โœ Scribed by Grieco, Paul A.; Nishizawa, Mugio; Burke, S. D.; Marinovic, N.


Book ID
127000874
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
217 KB
Volume
98
Category
Article
ISSN
0002-7863

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Reactlon of (5) with chloromethyl methyl ether undergoes successively stereo and regioselectlve alkylatlon. Compound (6) was subsequently transformed to the cls-fused angular vinyl 6-valerolactone (7). Vernolepln (1) and vernomenin (2), 1 novel elemanollde bls-a-methylenelactones, are the malor con