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Total synthesis of (+)-varitriol via a symmetrical furanose diol as the key intermediate

✍ Scribed by Lingaiah Nagarapu; Venkateswarlu Paparaju; Apuri Satyender; Rajashaker Bantu

Book ID
113930166
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
547 KB
Volume
52
Category
Article
ISSN
0040-4039

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An enantioselective route for the total synthesis of forskolin, a potent activator of adenylate cyclase, has been developed which is based on reduction of dienone 3 to the (S)-alcohol4 and conversion in two steps to tricyclic lactone 9, obtained in optically pure form simply by recrystallization. A