𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Total synthesis of the indole alkaloid (±)-tacamine

✍ Scribed by Mauri Lounasmaa; David Din Belle; Arto Tolvanen

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
255 KB
Volume
35
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthetic Studies T
ChemInform Abstract: Synthetic Studies Towards the Indole Alkaloid Tacamine. Part 4. Total Syntheses of Tacamine-Type Indole Alkaloids of Tabernaemontana eglandulosa.
✍ D. DIN BELLE; A. TOLVANEN; M. LOUNASMAA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Synthetic Studies Towards the Indole Alkaloid Tacamine. Part 4. Total Syntheses of Tacamine-Type Indole Alkaloids of Tabernaemontana eglandulosa. -Seven alkaloids (VI)-(VIII), (XII), and (XIV)-(XVI) are prepared via epimerization of the ester (II). However, attempted synthesis of the alkaloid (±)-19

Total Synthesis of the Indole Alkaloid V
Total Synthesis of the Indole Alkaloid Vallesiachotamine
✍ Priv.-Doz. Dr. Dietrich Spitzner; Prof. Dr. Ernest Wenkert 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc

Aldehyde Intermediates in the Synthesis
Aldehyde Intermediates in the Synthesis of Tacamine-Type Indole Alkaloids: Preparation of (±)-apotacamine
✍ Arto Tolvanen; David Din Belle; Mauri Lounasmaa 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 German ⚖ 394 KB

## Abstract The synthesis of aldehyde intermediates suitable for the preparation of indole alkaloids of the tacamine (1) type is described. The four possible aldehydes 4–7 were prepared from methyl 5‐ethylnicotinate (8) in a few simple steps using a base‐catalyzed epimerization as the final step (_