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ChemInform Abstract: Synthetic Studies Towards the Indole Alkaloid Tacamine. Part 4. Total Syntheses of Tacamine-Type Indole Alkaloids of Tabernaemontana eglandulosa.

✍ Scribed by D. DIN BELLE; A. TOLVANEN; M. LOUNASMAA

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199701284

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✦ Synopsis

Synthetic Studies Towards the Indole Alkaloid Tacamine. Part 4. Total Syntheses of Tacamine-Type Indole Alkaloids of Tabernaemontana eglandulosa. -Seven alkaloids (VI)-(VIII), (XII), and (XIV)-(XVI) are prepared via epimerization of the ester (II). However, attempted synthesis of the alkaloid (±)-19S-hydroxytacamine fails. -(DIN BELLE, D.; TOLVANEN,

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