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Total synthesis and stereochemical reassignment of the indole alkaloid vinoxine

✍ Scribed by Joan Bosch; M.-Lluïsa Bennasar; Ester Zulaica; Miguel Feliz


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
292 KB
Volume
25
Category
Article
ISSN
0040-4039

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Total Synthesis of the Indole Alkaloid V
✍ Priv.-Doz. Dr. Dietrich Spitzner; Prof. Dr. Ernest Wenkert 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc