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Total Synthesis of (−)-Cleistenolide

✍ Scribed by Kunz, Oliver; Biernat, Anne; Schmidt, Bernd

Book ID
115449880
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
856 KB
Volume
75
Category
Article
ISSN
0022-3263

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Total synthesis of (−)-cleistenolide
Total synthesis of (−)-cleistenolide
✍ Palakuri Ramesh; H.M. Meshram 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 365 KB

The total synthesis of (À)-cleistenolide, a novel natural product recently isolated from the annonaceae species cleistochlamys kirkii oliver, is described. The synthesis proceeds starting from easily accessible D-manitol using a selective benzoylation, a selective acetonide deprotection, silylprotec

Total Synthesis of (−)-Cleistenolide
Total Synthesis of (−)-Cleistenolide
✍ Dokuburra Chanti Babu; Kankati Ashalatha; Chitturi Bhujanga Rao; Jon Paul Selvam 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 153 KB

## Abstract An efficient and short total synthesis of (−)‐cleistenolide (**1**) from D‐mannitol with an overall yield of 23.6% is described. The chiron approach for the synthesis of (−)‐cleistenolide involves a one‐C‐atom __Wittig__ olefination, a selective allylic triethylsilyl protection, and a _