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Total synthesis of (−)-cleistenolide

✍ Scribed by Palakuri Ramesh; H.M. Meshram

Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
365 KB
Volume
52
Category
Article
ISSN
0040-4039

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✦ Synopsis

The total synthesis of (À)-cleistenolide, a novel natural product recently isolated from the annonaceae species cleistochlamys kirkii oliver, is described. The synthesis proceeds starting from easily accessible D-manitol using a selective benzoylation, a selective acetonide deprotection, silylprotection and ringclosing metathesis reaction.

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