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Total synthesis of aspergillide B and structural discrepancy of aspergillide A

✍ Scribed by Sudhir M. Hande; Jun’ichi Uenishi


Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
224 KB
Volume
50
Category
Article
ISSN
0040-4039

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Total synthesis of (+)-aspergillide C
✍ Makoto Kanematsu; Masahiro Yoshida; Kozo Shishido 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 541 KB

The enantioselective total synthesis of aspergillide C, a member of a novel class of 14-membered macrolides isolated from the marine-derived fungus Aspergillus ostianus strain 01F313, has been accomplished employing a highly diastereoselective intramolecular oxy-Michael reaction as the key step.