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Synthesis of aspergillide A from a synthetic intermediate of aspergillide B

✍ Scribed by Tomohiro Nagasawa; Shigefumi Kuwahara

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
419 KB
Volume
51
Category
Article
ISSN
0040-4039

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A total, stereoselective synthesis of the cytotoxic macrolide aspergillide B has been performed. A cross metathesis and a C-glycosidation via a Mukaiyama-type aldol reaction were key features of the synthesis. The macrocyclic lactone ring was created by means of the Yamaguchi procedure.