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Total synthesis of a B-ring “homoalkaloid”. 4,5,6,7,7a,8-Hexahydro-7-methylphenanthro[10,1-bc]azepine

✍ Scribed by Bruce L. Jensen; Michael A. Woods

Book ID
112125808
Publisher
Journal of Heterocyclic Chemistry
Year
1979
Tongue
English
Weight
210 KB
Volume
16
Category
Article
ISSN
0022-152X

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Synthesis of bridged analogs of epibatid
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The synthesis of conformationally locked analogs of epibatidine are described in which the key step is an intramolecular reductive palladium-catalyzed Heck-type coupling.

ChemInform Abstract: Synthesis of Bridge
ChemInform Abstract: Synthesis of Bridged Analogues of Epibatidine. 3-Chloro-5,7,8,9,9a,10-hexahydro-7,10-methanopyrrolo [1,2-b]-2,6-naphthyridine and 2-Chloro-5,5a,6,7,8,10-hexahydro-5,8-methanopyrrolo [2,1-b]-1,7-naphthyridine.
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