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Synthesis of bridged analogs of epibatidine. 3-Chloro-5,7,8,9,9a,10-hexahydro-7,10-methanopyrrolo[1,2-b]-2,6-naphthyridine and 2-chloro-5,5a,6,7,8,10-hexahydro-5,8-methanopyrrolo[2,1-b]-1,7-naphthyridine

✍ Scribed by Lawrence E Brieaddy; S Wayne Mascarella; Hernán A Navarro; Robert N Atkinson; M.I Damaj; Billy R Martin; F.Ivy Carroll

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
86 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of conformationally locked analogs of epibatidine are described in which the key step is an intramolecular reductive palladium-catalyzed Heck-type coupling.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of Bridge
ChemInform Abstract: Synthesis of Bridged Analogues of Epibatidine. 3-Chloro-5,7,8,9,9a,10-hexahydro-7,10-methanopyrrolo [1,2-b]-2,6-naphthyridine and 2-Chloro-5,5a,6,7,8,10-hexahydro-5,8-methanopyrrolo [2,1-b]-1,7-naphthyridine.
✍ Lawrence E. Brieaddy; S. Wayne Mascarella; Hernan A. Navarro; Robert N. Atkinson 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Synthesis of 2,4-Di
ChemInform Abstract: Synthesis of 2,4-Diamino-5,6,7,8,9,10-hexahydro-5,9-methanopyrimido[4,5-b]azocine.
✍ Edward C. Taylor; James E. Dowling; Beena Bhatia 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

## Synthesis of 2,4- 6,7,8,9,9methanopyrimido[4,azocine. -Optimization of direct annulation of triaminopyrimidine (I) with cyclohexenone (II) is achieved using acetic acid as solvent in a screw-capped pressure tube that is heated at 120 • C for 18 hours. Compound (VII) as prototype, its derivative