Total Synthesis of 7′-Desmethylkealiiquinone, 4′-Desmethoxykealiiquinone, and 2-Deoxykealiiquinone
✍ Scribed by Lima, Heather M.; Sivappa, Rasapalli; Yousufuddin, Muhammed; Lovely, Carl J.
- Book ID
- 124061137
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 514 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-3263
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The total synthesis of (+ j-o-CBT (16) was effected from the achiral f7-membered ketone 3 by a se uence featurin hydroxy directed epou P \*!& \* asymmetric reduction, diastereoselective [2,31 Wittig ring contraction and bon as stereochemically important steps.