Synthesis and thermolysis of 7,8-diazabicyclo[4.2.2]deca-2,4,7-triene
β Scribed by Olsen, Henrik; Snyder, James P.
- Book ID
- 125901866
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 398 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
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## Abstract Thermal transformation of 7,8βdiazabicyclo[4.2.2]decaβ2,4,7,9βtetraene __N__βoxide (**3**) was observed, (__Z__)βbenzaldehyde oxime being the major product, with (__E__)βbenzaldehyde oxime as a minor product. __N__βOxide **3** was labeled with deuterium Ξ± to the oxidized Nβatom. The loc
It was recently reported that the acetone-sensitized photoisomerisation of anti-7,8-beneotricyclo[4.2.2.0295 ]deca-3,7,9-triene (1) yields beneobasketene (2) and tetracyclic isomer (3).1 We now wish to describe our related studies on the photosensitiaed isomerization of (1) and some related compoun