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Thermal Isomerization of 7,8-Diazabicyclo[4.2.2]deca-2,4,7,9-tetraene N-oxide to Benzaldehyde Oxime

✍ Scribed by Henrik Olsen

Book ID: 102252370
Publisher: John Wiley and Sons
Year: 1982
Tongue: German
Weight: 287 KB
Volume: 65
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19820650625

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✦ Synopsis

Abstract

Thermal transformation of 7,8‐diazabicyclo[4.2.2]deca‐2,4,7,9‐tetraene N‐oxide (3) was observed, (Z)‐benzaldehyde oxime being the major product, with (E)‐benzaldehyde oxime as a minor product. N‐Oxide 3 was labeled with deuterium α to the oxidized N‐atom. The location of the deuterium label in the thermolysis products fitted one of two reasonable mechanisms.

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