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Thermal isomerization of bicyclo[4.2.2]deca-2,4,7,9-tetraene

✍ Scribed by Maitland Jones Jr.; Billy Fairless

Book ID: 104214084
Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 176 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72783-3

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✦ Synopsis

CENTRAL to the consideration of mechanism in many of the transformations of molecules of the formula (CH),, has been tetracyclo[4.4.0.02"0 .05"]deca-3,8-diene (I).3a-g We describe here a degenerate isomerization of bicyclo-[4.?.2]deca-2,4,7,9-tetraene (II) which most strongly implicates I as an intermediate.

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Im Zusammenhang mit unseren Untersuchungen am Bicycle [4. 3.1 ldecatrienylkation (A) oder methanoiiberbriickten Bishomotropyliumion r21 reizte uns die Synthese des Bicyclo[4. 3. 21 (z)