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Synthesis of 4-Acetylisocoumarin: First Total Syntheses of AGI-7 and Sescandelin

✍ Scribed by Kim, Sanghee; Fan, Gao-jun; Lee, Jaekwang; Lee, Jung Joon; Kim, Deukjoon


Book ID
111925216
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
52 KB
Volume
67
Category
Article
ISSN
0022-3263

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First Total Synthesis of (Β±)-Puyanin and
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## Abstract A facile approach for the first total synthesis of two naturally occurring geranylated flavonoids, (Β±)‐puyanin (**1**) and (Β±)‐4′‐__O__‐methylbonannione (**2**) has been obtained with total yields of 27% and 17.8%, respectively. The key steps were regioselective cyclization of geranylat