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Enantioselective total synthesis of (+)-α-2,7,11-cembratriene-4,6-diol (α-CBT)

✍ Scribed by James A. Marshall; Edward D. Robinson

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
238 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

The total synthesis of (+ j-o-CBT (16) was effected from the achiral f7-membered ketone 3 by a se uence featurin hydroxy directed epou P *!& * asymmetric reduction, diastereoselective [2,31 Wittig ring contraction and bon as stereochemically important steps.

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