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Total synthesis of Δ9(12)-capnellene-8α,10α-diol

✍ Scribed by Gerald Pattenden; Simon J. Teague

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
159 KB
Volume
23
Category
Article
ISSN
0040-4039

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Synthesis of Δ9(12)-capnellene-8β, 10α-d
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## Abstract The synthesis of the (±)‐form of the marine sesquiterpene (–)‐Δ^9(12)^‐capnellene (**1**) by double application of the __a__‐alkynone cyclization is described. Starting with 2, 2, 5‐trim ethylcyclopentanone (**2**), the elaboration of the tricyclo [6.3.0.0^2,6^]undecane C‐skeleton of **