The first total synthesis of the unusual capnellenediol(l), found in the soft coral Capnella imbrica, is described. A9(12) -Capnellene-88,lOa-dial(1) co-occurs with related alcohols and
✦ LIBER ✦
Synthetic studies on capnellol family : an improved synthesis of Δ9(12)-capnellene-3β,8β,10α-triol and the first total synthesis of Δ9(12)-capnellene-β,8β,10α,14-tetrol
✍ Scribed by Toshiaki Mase; Masakatsu Shibasaki
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 261 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A much improved synthesis of a 9(12)_ capnellene-3a,8a,lOn-triol and
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## Abstract __Zusammenfassung__. Im Rahmen der vorliegenden Mitteilung berichten wir über den partial‐synthetischen Aufbau von 3‐Oxo‐17 β‐acetoxy‐14α‐methyl‐Δ^4^‐8α, 9β, 10α, 13α‐östren (**12**), dessen Struktur anschliessend mittels dreidimensionaler Röntgenanalyse [2] sichergestellt worden ist. A