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Total syntheses of (±)-cis- and (±)-trans-neocnidilides

✍ Scribed by Mahadevegowda, Surendra H.; Khan, Faiz Ahmed

Book ID
125483246
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
733 KB
Volume
55
Category
Article
ISSN
0040-4039

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Total syntheses of (±)-cis- and trans-11
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✍ Kalle Rönkkö; Mathias Berner; Reija Jokela; Arto Tolvanen 📂 Article 📅 2000 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 302 KB

## Abstract The total syntheses of 11‐methoxydeethyleburnamonines (**4**) and (**13**) were carried out with use of 6‐methoxytryptophyl bromide (**5**) as starting material. Compound **5** was converted in three steps to __trans__‐ester **8**. Acid‐catalysed epimerization of **8**, lithium aluminum